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Memory Alpha
Pi debris

Debris of the Pi

You may also be looking for pi, the Greek letter.

The Pi was a Romulan scout ship in service during the 24th century.

In 2366, the Pi, crewed by Patahk and Centurion Bochra, was carrying out a covert mission when it crash-landed on the planet Galorndon Core, inside Federation space. The Pi was destroyed with an ultritium explosive after the crash to prevent its capture by Starfleet. Both Romulan crew members were eventually retrieved by the USS Enterprise-D. Patahk died from his injuries, while Bochra was returned to the Romulans. What the Pi was doing at Galorndon Core was never determined. (TNG: "The Enemy")

The name Pi was later used for a Romulan scout ship in the game Star Trek: Armada.
Pi is a Greek letter, although it is unknown if there is any relation. In this usage, though, the 'relationship' is most likely simply homophonic.
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